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Encyclopedia: Paper, The Paper, Academic publishing, Electronic paper, Toilet paper, punched tape, Paper shredder, Chad (paper), Paper Mario, Paper size

Paper is a thin material produced by the amalgamation of plant fibres, which are subsequently held together without extra binder, largely by hydrogen bonds and to a large degree by fiber entanglement. The fibres used are usually natural and composed of cellulose. The most common source of these kinds of fibres is wood pulp from pulpwood trees, largely softwoods such as spruce. However, other vegetable fibre materials including cotton, hemp, linen, and rice may be used.

Manufacturing

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Whether done by hand or with a paper machine, the paper making process has three simple steps:

Preparation of the fibers

Wood or plant cell walls are composed of fibers bound together. During pulping, these fibers are separated from each other and carbohydrate surfaces (cellulose or hemicellulose) are exposed. It is hydrogen bonding between these carbohydrate surfaces that provides paper strength. Fibers can be separated either chemically or mechanically.

Most chemical pulp is made using the Kraft process. The purpose of a chemical pulping process is to break down the chemical structure of lignin and render it soluble in the cooking liquor, so it may be washed from the cellulose fibers. Because lignin holds the plant cells together, chemical pulping frees the fibers and makes pulp. After Kraft pulping the pulp can be used directly for bags and boxes or further delignifed, during bleaching, to produce white pulp for printing and writing. Chemical pulps tend to cost more than mechanical pulps, largely due to the low yield, 40-50% of the original wood. Since the process preserves fiber length, however, chemical pulps tend to make stronger paper. Another advantage of chemical pulping is that the majority of the heat and electricity needed to run the process is produced by burning the lignin removed during pulping.

There are two major mechanical pulps, thermomechanical pulp (TMP) and groundwood. In the TMP process wood is chipped and then fed into large steam-heated refiners where the chips are squeezed and fiberized between two steel discs. In the groundwood process debarked logs are fed in into grinders where they are pressed against a rotating stones and fiberized. Mechanical pulping does not remove the lignin, so the yield is very high, > 95%, but also causes paper made from this pulp to yellow and become brittle over time. Mechanical pulps have rather short fiber lengths and produce weak paper. Although large amounts of electrical energy are required to produce mechanical pulp, it costs less than chemical pulp.

Paper made from either chemical or mechanical pulp can also be recycled. By mixing with water and applying mechanical action the hydrogen bonds in the paper can be broken and fibers separated again.

Sheet formation

The pulp mixture is further diluted with water resulting in a very thin slurry. This dilute slurry is drained through a fine-mesh moving screen to form a fibrous web, a long continuous sheet. Water from the slurry is drained through the screen and the resulting paper is pressed, dried and at the end of the process, is fed into a roll.

While it is still wet, a watermark woven into the continuous screen may be impressed into the paper. Visible when the finished paper is held to the light, a watermark is used on paper currency and on finer quality paper to identify the manufacturer and establish authenticity.

In the traditional mould process, a quantity of pulp is placed into a form, with a wire-mesh base, so that the fibres form a sheet on the mesh and excess water can drain away. Pressure may be applied to help remove additional water. The paper may then be removed from the mould, wet or dry, and go on to further processing.

Most mass-produced paper is made using the continuous Fourdrinier process to form a reel or web of fibres in a thin sheet. When dried, this continuous web may be cut into rectangular sheets by slicing the web vertically and horizontally to the desired size. Standard sheet sizes are prescribed by governing bodies such as the International Organization for Standardization (ISO).

Drying

After the paper web is produced, the water must be removed from it in order to create a usable product. This is accomplished through pressing and drying. The methods of doing so vary between the different processes used to make paper, but the concepts remain the same.

Pressing the sheet removes the water by force. Once the water is forced from the sheet, another absorbant material must be used to collect this water. On a paper machine this is called a felt (not to be confused with the traditional felt). When making paper by hand, a blotter sheet is used.

Drying involves using air and or heat to remove water from the paper sheet. In the earliest days of papermaking this was done by hanging the paper sheets like laundry. In more modern times, various forms of heated drying mechanisms are used. On the paper machine, the most common is the steam-heated can dryer. These dryer cans heat to temperatures above 200ºF and are used in long sequences of more than 40 cans. The heat produced by these can easily dry the paper to less than 6% moisture.

The paper may then undergo "sizing" to alter its physical properties for use in various applications.

Applications

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*To write or print on: the piece of paper becomes a document; this may be for keeping a record (or in the case of printing from a computer or copying from another paper: an additional record) and for communication; see also reading.

*To represent a value:
**paper money
**bank note
**check
**security
**voucher
**ticket
*For entertainment:
**book
**magazine
**newspaper
**art
**zine
*For packaging:
**corrugated box
**paper bag
**envelope
**wrapping tissue
**wallpaper
*For cleaning (see also tissue, Kleenex):
**toilet paper
**handkerchiefs
**paper towels
**cat litter
*For construction
**papier-mâché
**origami
**quilling
**Paper honeycomb, used as a core material in composite materials
**paper engineering, see also construction paper
*Other uses
**emery paper
**sandpaper
**blotting paper
**litmus paper
**universal indicator paper

Types

*Construction paper/sugar paper
*Cotton paper
*Electronic paper
*Inkjet paper
*Leather paper
*pH Indicator paper
**Litmus paper
**Universal indicator paper
*Photographic paper
*Plain paper

*Recycled paper
*Rice paper
*Sandpaper
*Tracing paper
*Tyvek paper
*Wallpaper
*Washi
*Wax paper
*Wet and Dry Paper
*Coated paper: glossy and matt surface
*Uncoated paper, also named wood free paper

History

Old World

The word paper comes from the ancient Egyptian writing material called papyrus, which was woven from papyrus plants. Papyrus was produced as early as 3000 BC in Egypt, and in ancient Greece and Rome. Further north, parchment or vellum, made of processed sheepskin or calfskin, replaced papyrus, as the papyrus plant requires subtropical conditions to grow. In China, documents were ordinarily written on bamboo, making them very heavy and awkward to transport. Silk was sometimes used, but was normally too expensive to consider. Indeed, most of the above materials were rare and costly.

While the Chinese court official Cai Lun is widely regarded to have first described the modern method of papermaking (inspired from wasps and bees) from wood pulp in AD 105, the 2006 discovery of specimens bearing written characters in north-west China's Gansu province suggest that paper was in use by the ancient Chinese military more than 100 years before Cai in 8 BCE http://news.xinhuanet.com/english/2006-08/08/content_4937457.htm. Archæologically however, true paper without writing has been excavated in China dating from the 2nd-century BCE. Paper is considered to be one of the Four Great Inventions of Ancient China. It spread slowly outside of China; other East Asian cultures, even after seeing paper, could not figure out how to make it themselves. Instruction in the manufacturing process was required, and the Chinese were reluctant to share their secrets. The technology was first transferred to Korea in 604 and then imported to Japan by a Buddhist priest, Dam Jing (曇徴) from Goguryeo, around 610, where fibres (called bast) from the mulberry tree were used.

After further commercial trading and the defeat of the Chinese in the Battle of Talas, the invention spread to the Middle East, where it was adopted in India and subsequently in Italy in about the 13th century, as an import from Islamic Spain. They used hemp and linen rags as a source of fibre. The oldest known paper document in the West is the Mozarab Missal of Silos from the 11th century, probably written in the Islamic part of Spain. Paper is recorded as being manufactured in both Italy and Germany by 1400, just about the time when the woodcut printmaking technique was transferred from fabric to paper in the old master print and popular prints.

Some historians speculate that paper was the key element in global cultural advancement. According to this theory, Chinese culture was less developed than the West in ancient times prior to the Han Dynasty because bamboo, while abundant, was a clumsier writing material than papyrus; Chinese culture advanced during the Han Dynasty and preceding centuries due to the invention of paper; and Europe advanced during the Renaissance due to the introduction of paper and the printing press.

In the very small quantities needed for popular prints , paper was affordable by the European urban working class and many peasants even in the 1400's, but books remained expensive until the nineteenth century. However even poor families could often afford a few by the 1700s in England, if they so chose.

Paper remained relatively expensive, at least in book-sized quantities, through the centuries, until the advent of steam-driven paper making machines in the 19th century, which could make paper with fibres from wood pulp. Although older machines predated it, the Fourdrinier paper making machine became the basis for most modern papermaking. Together with the invention of the practical fountain pen and the mass produced pencil of the same period, and in conjunction with the advent of the steam driven rotary printing press, wood based paper caused a major transformation of the 19th century economy and society in industrialized countries. With the introduction of cheaper paper, schoolbooks, fiction, non-fiction, and newspapers became gradually available to all the members of an industrial society by 1900. Cheap wood based paper also meant that keeping personal diaries or writing letters became universal. The clerk, or writer, ceased to be a high-status job, and by 1850 had nearly become an office worker or white-collar worker , which transformation can be considered as a part of the industrial revolution.

Unfortunately, the original wood-based paper was more acidic and more prone to disintegrate over time, through processes known as slow fires. Documents written on more expensive rag paper were more stable. The majority of modern book publishers now use acid-free paper.

New World

In America, archaeological evidence indicates that paper was invented by the Mayas no later than the 5th century AD.http://www.mathcs.duq.edu/~tobin/maya/ The Construction of the Codex In Classic- and Postclassic-Period Maya Civilization Maya Codex and Paper Making Called Amate, it was in widespread use among Mesoamerican cultures until the Spanish conquest. In small quantities, traditional Maya papermaking techniques are still practiced today.

The future of paper

Paper made in the west since the industrial revolution has been almost exclusively wood based, except for a few specialized papers like those used in banknotes. However, at least one company (Cloudy Bay Cotton) has recently tried to introduce cotton based tissue papers to westernised countries as an alternative to wood based ones. Their reasons for doing this are that the cotton based tissue papers are less abrasive and less likely to cause allergic reactions. The type of cotton fibres used for making paper are discarded as unusable waste from the textile industry, and can be manufactured using fewer chemicals and less energy.

Some manufacturers, notably AMD, have started using a new, slightly more environmentally friendly alternative to expanded plastic packaging made out of paper, known commercially as paperfoam. The packaging has very similar mechanical properties to some expanded plastic packaging, but is biodegradable and can also be recycled with ordinary paper. http://www.paperfoam.com/

With increasing environmental concerns about synthetic coatings (such as PFOA) and the currently higher prices of hydrocarbon based petrochemicals, there is a recent focus on zein (corn protein) as a coating for paper in high grease applications such as popcorn bags. http://v3.espacenet.com/textdoc?DB=EPODOC&IDX=WO2006002346&F=0

Synthetics such as Tyvek and Teslin have been introduced as printing media as a more durable material than paper.

In 2006, the world's first "Paper Technology Centre" was opened in Heidenheim, Germany, the headquarters of the Voith paper machine company, at a cost of 75 million Euros http://www.voithpaper.de/vp_e_grpdiv_history_today.htm.